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1913 Liberty Head Nickel
2-28-2007 - From Wikipedia

The 1913 Liberty Head nickel is one of the best-known and most coveted rarities in American numismatics. Only five examples are known to exist: two in museums and three in private collections.

The Indian Head ("Buffalo") nickel was introduced in February of 1913, replacing the Liberty Head design. These were the first official strikings of nickels in 1913; the Mint's official records do not record any Liberty Head nickels produced that year. Liberty Head nickels dated 1913 first came to the attention of the numismatic community in 1920. All five were in the possession of Samuel Brown, a numismatist who attended the American Numismatic Association's annual convention and displayed the coins there. Brown had previously placed an advertisement in The Numismatist in December 1919 seeking information on these coins and offering to pay $500 for each.

Ostensibly, the coins had been purchased as a result of this offer. However, Samuel Brown had been a Mint employee in 1913, and many numismatic historians have concluded that he was therefore responsible for striking the coins himself and then removing them from the Mint.
....this would not have been a unique occurrence; such clandestine strikes were actually quite common in the 19th century,
If true, this would not have been a unique occurrence; such clandestine strikes were actually quite common in the 19th century, with the Class II and III 1804 silver dollars being perhaps the best-known instance. Other numismatic authorities, such as Q. David Bowers, have questioned this scenario, and pointed out that there are several methods by which the coin could have been legitimately producedIn January 1924, Samuel Brown sold all five 1913 Liberty Head nickels. The intact lot passed through the hands of several other coin dealers before finally being purchased by Colonel E.H.R. Green (son of the infamous miser Hetty Green). Green kept them in his collection until his death in 1936. His estate was then auctioned off, and all five of the 1913 Liberty Head nickels were purchased by two dealers, Eric P. Newman and B.G. Johnson. The dealers broke up the set for the first time.